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From Terraria Wiki
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The Buccaneer costume is a vanity set made up of the Buccaneer Bandana, the Buccaneer Tunic and the Buccaneer Pantaloons. These items are all supposed to be equipped in the Social Slots as they only provide a visual appearance.
They can be obtained as a rare drop from any Pirate Invasion enemy, except the Pirate Captain and Parrots.
- It was originally suggested by Leinfors (Terraria Forum moderator).